Fluorides

Fluoride glass is a class of non-oxide optical quality glasses composed of fluorides of various metals. Because of their low viscosity, it is very difficult to completely avoid crystallization while processing it through the glass transition (or drawing the fiber from the melt). Thus, although heavy metal fluoride glasses (HMFG) exhibit very low optical attenuation, they are not only difficult to manufacture, but are quite fragile, and have poor resistance to moisture and other environmental attacks. Their best attribute is that they lack the absorption band associated with the hydroxyl (OH) group (3200–3600 cm−1), which is present in nearly all oxide-based glasses.

An example of a heavy metal fluoride glass is the ZBLAN glass group, composed of zirconium, barium, lanthanum, aluminium, and sodium fluorides. Their main technological application is as optical waveguides in both planar and fiber form. They are advantageous especially in the mid-infrared (2000–5000 nm) range.

HMFGs were initially slated for optical fiber applications, because the intrinsic losses of a mid-IR fiber could in principle be lower than those of silica fibers, which are transparent only up to about 2 μm. However, such low losses were never realized in practice, and the fragility and high cost of fluoride fibers made them less than ideal as primary candidates. Later, the utility of fluoride fibers for various other applications was discovered. These include mid-IR spectroscopy, fiber optic sensors, thermometry, and imaging. Also, fluoride fibers can be used for guided lightwave transmission in media such as YAG (yttria-alumina garnet) lasers at 2.9 μm, as required for medical applications (e.g. ophthalmology and dentistry).

June 3, 2011

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