The propagation of light through the core of an optical fiber is based on total internal reflection of the lightwave. Rough and irregular surfaces, even at the molecular level, can cause light rays to be reflected in random directions. This is called diffuse reflection or scattering, and it is typically characterized by wide variety of reflection angles.
Light scattering depends on the wavelength of the light being scattered. Thus, limits to spatial scales of visibility arise, depending on the frequency of the incident light-wave and the physical dimension (or spatial scale) of the scattering center, which is typically in the form of some specific micro-structural feature. Since visible light has a wavelength of the order of one micrometer (one millionth of a meter) scattering centers will have dimensions on a similar spatial scale.
Thus, attenuation results from the incoherent scattering of light at internal surfaces and interfaces. In (poly)crystalline materials such as metals and ceramics, in addition to pores, most of the internal surfaces or interfaces are in the form of grain boundaries that separate tiny regions of crystalline order. It has recently been shown that when the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent. This phenomenon has given rise to the production of transparent ceramic materials.
Similarly, the scattering of light in optical quality glass fiber is caused by molecular level irregularities (compositional fluctuations) in the glass structure. Indeed, one emerging school of thought is that a glass is simply the limiting case of a polycrystalline solid. Within this framework, "domains" exhibiting various degrees of short-range order become the building blocks of both metals and alloys, as well as glasses and ceramics. Distributed both between and within these domains are micro-structural defects that provide the most ideal locations for light scattering. This same phenomenon is seen as one of the limiting factors in the transparency of IR missile domes.
At high optical powers, scattering can also be caused by nonlinear optical processes in the fiber.
May 2, 2012